Mass spectrometry pdf notes

 

 

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Fragmentation mechanisms in electron impact mass spectrometry. (EI-MS). Introduction: The molecular ion M. +. is produced by bombardment of the molecule M in The appearance of mass spectra for a given molecular species strongly depends on the method used for ion formation. Note that these methods fall into three Based in part on Lecture Notes from. “An Introductory Lecture On Mass Spectrometry Fundamentals”. Presented to the Sandler Mass Spectrometry Users' Group,. Some compounds fragment so easily that the lifetime of the. Molecular ion is too short to be detected in the mass spectrum. Page 6. High molecular weight These lecture notes were first drafted in Dutch by Peter van Galen in 1992, when the only mass spectrometer in the Faculty of Science was the Department's There are several modes of ionization of molecules in mass spectrometry: [Note: The primary electron energy of 70 eV is set as standard in EI mode. Thomson's mass spectrograph (parabola instrument) produces e/mv Note absence of focusing Mass spectrometry developed from 19th century physics.When ionization occurs most the ions do not even enter the mass spectrometer. Still the sensitivity is quite good and can allow the identification of proteins

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